A 3-1 victory set up a meeting with Brazil, who they beat in the final of the 1998 World Cup.
Bayern Munich earned a nervous 1-0 win at St Pauli thanks to a sensational 28-metre drive from Jamal Musiala to stay unbeaten.
Champions Leverkusen, who set a European record of 51 consecutive games without loss across all competitions last season, kept their unbeaten streak intact with a number of late equalisers.
Barcelona captain Raphinha scored twice as they returned to winning ways in LaLiga for the first time in a month with a 5-1 victory at Mallorca on Tuesday.
Atalanta beat Bayer Leverkusen 3-0 in the Europa League final
Schick on target again as Leverkusen win, Leipzig thrashed 5-1
IMAGES from the Europa League semifinal matches played on Thursday.
A round-up of Wednesday's UEFA Champions League last-16 first leg matches.
Germany and Real Madrid midfielder Sami Khedira has had successful surgery on torn knee ligaments and he may be available for the World Cup, according to Germany team doctor Hans-Wilhelm Mueller-Wohlfahrt.
Barcelona's Ferran Torres scored twice to help secure a late 4-2 comeback win at Atletico Madrid in a pulsating LaLiga clash on Sunday.
Former Real Madrid president Ramon Calderon has claimed that star forward Cristiano Ronaldo could make a return to Manchester United because he is disillusioned at the La Liga side.
Robert Lewandowski's brace earned depleted Barcelona a 2-1 comeback win at Valencia
An all-conquering Spain side were on the crest of a wave last time they faced Germany on the way to winning the 2010 World Cup but they now meet on Tuesday in what will be a stern test for a new fledgling team.
It will be the fifth edition in a row that the two heavyweights have met head to head at a European Championship.
Barcelona's Neymar struck twice to put the Spanish side in the Champions League final despite a 3-2 loss at Bayern Munich on Tuesday as they progressed 5-3 on aggregate and will face Real Madrid or Juventus next month.
Jose Mourinho's side top Group G with a maximum nine points, three clear of second-placed Slavia.
Cristiano Ronaldo will avoid serving a 23-month prison sentence after agreeing a deal.
A summary of the concluding day's action in the German Cup, French Cup and La Liga.
AC Milan coach Sinisa Mihajlovic has dismissed complaints about a Nigel de Jong tackle during Tuesday's friendly match against Bayern Munich by saying that "football is not ballet."
Liverpool are determined to end the trend of selling their best players during the close season in order to build a squad capable of consistently challenging for major honours, manager Juergen Klopp said.
Croatian forward Ante Budimir scored twice to help Osasuna earn a shock 4-2 home win over leaders Barcelona.
Bayer Leverkusen beat Freiburg 3-2 to edge closer to a first ever Bundesliga title.
Robert Lewandowski's hat-trick helped give coach Carlo Ancelotti a flying start to his first Bundesliga campaign as Bayern Munich cruised to an easy 6-0 win over Werder Bremen at the Allianz Arena on Friday.
Several players across the continent are poised to make a name for themselves on the international stage.
IMAGES from the UEFA Champions League matches played on Tuesday.
Robert Lewandowski struck twice to steer champions Bayern Munich to a 2-1 win at Hamburg SV on Friday that stretched their lead at the top to 11 points as the Bundesliga resumed following a one-month winter break.
Bayer Leverkusen crushed hosts VfL Bochum 5-0 to stretch their remarkable unbeaten run across all competitions this season to 50 consecutive matches.
Leverkusen's Schick scores hat-trick in comeback win over Heidenheim.
Former world champions Spain will have to wait to regain their past glory but they need not discard their attractive brand of football that earned them fans and laurels, World Cup-winning defender Joan Capdevila told Reuters in an interview.
Spain coach Vicente del Bosque has called Atletico Madrid's Brazil-born forward Diego Costa into his squad for the first time for this month's friendlies away to Equatorial Guinea and South Africa.
Holders Barcelona will face fellow Spaniards Atletico Madrid, runners-up two seasons ago, in the Champions League quarter-finals following the draw in Nyon on Friday.
Tottenham Hotspur have appointed former Celtic coach Ange Postecoglou as their new manager on a four-year contract.
La Liga leaders Real Madrid cruised to a 4-0 home win over relegation-threatened Celta Vigo on Sunday to restore their seven-point lead at the top of the table with a dominant display.
Bayern Munich's surprise 3-1 Champions League loss to Porto was the price the five-time European champions paid for a string of injuries and a tired squad.
Arjen Robben grabbed his 100th goal for the club as undefeated Bayern Munich outclassed Freiburg 2-0.
Arjen Robben scored a 90th minute winner in their 2-1 victory at Mainz 05 on Friday to send Bundesliga leaders Bayern Munich into the winter break with a commanding 14-point lead.
Chile overwhelmed an out-of-sorts Spain 2-0 to join the Netherlands in the second round of the World Cup and eliminate the defending champions on a memorable night at the Maracana on Wednesday.
Atletico Madrid secured a hard-fought 2-1 home victory over Real Betis in La Liga on Sunday thanks to an own-goal by Rui Silva and a header by Alvaro Morata as Diego Simeone's side ended a three-game winless run in all competitions.
IMAGES from the UEFA Champions League matches played on Wednesday.